Exact solution for anisotropic diffusion-controlled reactions with partially reflecting conditions.
نویسندگان
چکیده
We investigate a generalization of the model of Solc and Stockmayer to describe the diffusion-controlled reactions between chemically anisotropic reactants taking into account the partially reflecting conditions on two parts of the reaction surface. The exact solution of the relevant mixed boundary-value problem was found for different ratios of the intrinsic rate constants. The results obtained may be used to test numerical programs that describe diffusion-controlled reactions in real systems of particles with anisotropic reactivity.
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عنوان ژورنال:
- The Journal of chemical physics
دوره 127 18 شماره
صفحات -
تاریخ انتشار 2007